Radiation Protection Dosimetry Advance Access originally published online on August 20, 2008
Radiation Protection Dosimetry 2008 132(1):42-50; doi:10.1093/rpd/ncn215
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High-sensitive CaSO4:Dy thermoluminescent phosphor synthesis by co-precipitation technique
1 Radiological Safety Division, Safety Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102, Tamil Nadu, India
* Corresponding author: arunachalamlakshmanan{at}yahoo.com
Received May 17, 2008, amended July 16, 2008, accepted July 23, 2008
This paper describes the successful development of the co-precipitation technique for the preparation of a high-sensitive dysprosium-doped calcium sulphate (CaSO4:Dy) thermoluminescent dosimetry (TLD) phosphor with dosimetric glow peak at
230°C which is a desired development in the field of radiation protection dosimetry. The main advantages of this co-precipitation technique over the conventional recrystallisation technique of phosphor preparation are: (i) preparation time is very less; (ii) quantity of sulphuric acid evaporated is insignificant; (iii) higher TL sensitivity –20% more than the present material; (iv) better glow curve structure; (v) lesser glow peak shift and better linearity to gamma and (vi) uniform crystal morphology and lower grain size—all grains are mostly cuboidal in shape, quite uniform and small (average size about 25 µm), suitable for manufacturing teflon discs in as-prepared form. Optimum values of various parameters in the method of preparation for a batch of 20 g CaSO4:Dy phosphors to obtain maximum TL sensitivity, with favourable glow curves are studied.
2 Present address: Saveetha Engineering College, Thandalam, Chennai 602105, India